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Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

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Abstract

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon–fluorine bond cleavage and carbon–silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

Graphical abstract: Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

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Publication details

The article was received on 11 Jul 2019, accepted on 05 Aug 2019 and first published on 05 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC05325E
Chem. Commun., 2019, Advance Article

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    Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

    X. Wang, Z. Wang and Y. Nishihara, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC05325E

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