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Issue 71, 2019
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NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas–solid single crystal to single crystal reactions

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Abstract

A bridging nitrite and a nitrate counter anion per Co2 site are generated in-crystal and an arylamine group on the ligand scaffold is oxidised to a nitro group when nitric oxide (NO) is chemisorbed by molecular crystals of cobalt complexes.

Graphical abstract: NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas–solid single crystal to single crystal reactions

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Article information


Submitted
10 Jul 2019
Accepted
05 Aug 2019
First published
15 Aug 2019

Chem. Commun., 2019,55, 10551-10554
Article type
Communication

NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas–solid single crystal to single crystal reactions

M. S. Møller, A. Haag, V. McKee and C. J. McKenzie, Chem. Commun., 2019, 55, 10551
DOI: 10.1039/C9CC05315H

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