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NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas–solid single crystal to single crystal reactions

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Abstract

A bridging nitrite and a nitrate counter anion per Co2 site are generated in-crystal and an arylamine group on the ligand scaffold is oxidised to a nitro group when nitric oxide (NO) is chemisorbed by molecular crystals of cobalt complexes.

Graphical abstract: NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas–solid single crystal to single crystal reactions

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Publication details

The article was received on 10 Jul 2019, accepted on 05 Aug 2019 and first published on 15 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC05315H
Chem. Commun., 2019, Advance Article

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    NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas–solid single crystal to single crystal reactions

    M. S. Møller, A. Haag, V. McKee and C. J. McKenzie, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC05315H

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