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DABCO-mediated [3+3] annulation of para-quinamines: access to functionalized 1,2,4-triazinone derivatives

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Abstract

An unprecedented [3+3]-annulation of p-quinamines and nitrile imines was developed, affording a series of 1,2,4-triazinone derivatives in moderate to excellent yields with excellent diastereoselectivity. This cycloaddition expands the scope of p-quinamines to the construction of six-membered nitrogen-containing heterocyclic compounds.

Graphical abstract: DABCO-mediated [3+3] annulation of para-quinamines: access to functionalized 1,2,4-triazinone derivatives

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Publication details

The article was received on 09 Jul 2019, accepted on 31 Jul 2019 and first published on 31 Jul 2019


Article type: Communication
DOI: 10.1039/C9CC05276C
Chem. Commun., 2019, Advance Article

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    DABCO-mediated [3+3] annulation of para-quinamines: access to functionalized 1,2,4-triazinone derivatives

    Y. Zhu, H. Jin and Y. Huang, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC05276C

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