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Issue 69, 2019
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Stabilization of a new nanocomposite family by reduction of gold nanoclusters with electron-reservoir complexes

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Abstract

Four stable 19-electron Fe and Co sandwich electron-reservoirs and three hydride reservoir complexes reduce the prototypal nanocluster Au25(SR)18 (R = CH2CH2Ph) leading to a largely increased kinetic stabilization of the anionic nanocluster form compared to previously known nanocluster anion salts; these salts represent new and robust nanocomposite anionic gold clusters with 18-electron sandwich complexes as counter cations.

Graphical abstract: Stabilization of a new nanocomposite family by reduction of gold nanoclusters with electron-reservoir complexes

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Publication details

The article was received on 09 Jul 2019, accepted on 02 Aug 2019 and first published on 07 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC05260G
Chem. Commun., 2019,55, 10277-10280

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    Stabilization of a new nanocomposite family by reduction of gold nanoclusters with electron-reservoir complexes

    F. Fu, A. Dedieu, W. Wang, T. Chen, Y. Song, E. Fouquet, J. Hamon, M. Zhu and D. Astruc, Chem. Commun., 2019, 55, 10277
    DOI: 10.1039/C9CC05260G

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