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Issue 67, 2019
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Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster

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Abstract

We report how only one electron transfer from the hydrophilic reduced cluster [{Re6Se8}(CN)6]4− induces both a dramatic increase of the host–guest affinity with γ-cyclodextrin and a drastic alteration of the supramolecular dynamics. This striking behaviour, underlined by its thermochemical fingerprint, indicates that the self-assembly process is driven by a chaotropic effect.

Graphical abstract: Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster

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Publication details

The article was received on 04 Jul 2019, accepted on 24 Jul 2019 and first published on 25 Jul 2019


Article type: Communication
DOI: 10.1039/C9CC05136H
Chem. Commun., 2019,55, 9951-9954

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    Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster

    A. A. Ivanov, C. Falaise, D. Landy, M. Haouas, Y. V. Mironov, M. A. Shestopalov and E. Cadot, Chem. Commun., 2019, 55, 9951
    DOI: 10.1039/C9CC05136H

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