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Hierarchical multi-shell 66-nuclei silver nanoclusters trapping subvalent Ag6 kernels

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Abstract

Hierarchical nano structures are hard to fabircate. Here, we present three novel hierarchical multi-shell 66-nuclei silver nanoclusters, trapping ultrasmall Ag64+ nano-fragments by nine MoO42− ions. This Ag6@(MoO4)9 core is further wrapped by an outer Ag60 shell. The Ag6 kernel evolves from reduction involving DMF solvent. Carboxylate ligands are very important in the modulation of the polygon patterns on the Ag60 shell.

Graphical abstract: Hierarchical multi-shell 66-nuclei silver nanoclusters trapping subvalent Ag6 kernels

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Publication details

The article was received on 02 Jul 2019, accepted on 01 Aug 2019 and first published on 01 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC05044B
Chem. Commun., 2019, Advance Article

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    Hierarchical multi-shell 66-nuclei silver nanoclusters trapping subvalent Ag6 kernels

    Z. Wang, F. Yang, Y. Yang, Q. Liu and D. Sun, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC05044B

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