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Chiral double stapled o-OPEs with intense circularly polarized luminescence

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Abstract

Intrinsically chiral double stapled ortho-oligo phenylene ethynylenes (o-OPEs) 1 show glum values up to 5.5 × 10−2, the second highest value ever observed for a simple organic molecule (SOM). DFT calculations of molecular spectra and properties encompassing electric and magnetic dipole transition moments account for these observations.

Graphical abstract: Chiral double stapled o-OPEs with intense circularly polarized luminescence

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Publication details

The article was received on 25 Jun 2019, accepted on 09 Aug 2019 and first published on 12 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC04885E
Chem. Commun., 2019, Advance Article

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    Chiral double stapled o-OPEs with intense circularly polarized luminescence

    P. Reine, A. G. Campaña, L. Alvarez de Cienfuegos, V. Blanco, S. Abbate, A. J. Mota, G. Longhi, D. Miguel and J. M. Cuerva, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC04885E

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