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Issue 72, 2019
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Chiral double stapled o-OPEs with intense circularly polarized luminescence

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Abstract

Intrinsically chiral double stapled ortho-oligo phenylene ethynylenes (o-OPEs) 1 show glum values up to 5.5 × 10−2, the second highest value ever observed for a simple organic molecule (SOM). DFT calculations of molecular spectra and properties encompassing electric and magnetic dipole transition moments account for these observations.

Graphical abstract: Chiral double stapled o-OPEs with intense circularly polarized luminescence

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Article information


Submitted
25 Jun 2019
Accepted
09 Aug 2019
First published
12 Aug 2019

Chem. Commun., 2019,55, 10685-10688
Article type
Communication

Chiral double stapled o-OPEs with intense circularly polarized luminescence

P. Reine, A. G. Campaña, L. Alvarez de Cienfuegos, V. Blanco, S. Abbate, A. J. Mota, G. Longhi, D. Miguel and J. M. Cuerva, Chem. Commun., 2019, 55, 10685
DOI: 10.1039/C9CC04885E

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