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Issue 69, 2019
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Pd-catalyzed cascade reactions involving skipped dienes: from double carbopalladation to remote C–C cleavage

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Abstract

We report two ligand-controlled cascade reactions relying on the intramolecular carbopalladation of skipped dienes. The use of a bulky monodentate phosphine ligand affords [4,5]-spirocycles via sequential double carbopalladation, however bidentate phosphines promote a remote β-C-elimination process which does not rely on the use of strained or sterically hindered substrates.

Graphical abstract: Pd-catalyzed cascade reactions involving skipped dienes: from double carbopalladation to remote C–C cleavage

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Publication details

The article was received on 23 Jun 2019, accepted on 01 Aug 2019 and first published on 05 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC04817K
Chem. Commun., 2019,55, 10281-10284

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    Pd-catalyzed cascade reactions involving skipped dienes: from double carbopalladation to remote C–C cleavage

    H. Azizollahi, V. P. Mehta and J. García-López, Chem. Commun., 2019, 55, 10281
    DOI: 10.1039/C9CC04817K

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