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A self-catalyzed reaction of 1,2-dibenzoyl-o-carborane with hydrosilanes – formation of new hydrofuranes

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Abstract

The activation of Si–H bonds is a very important transformation both in organic and inorganic chemistry. Herein we report that 1,2-dibenzoyl-o-carborane (1) reacts with Si–H bonds, yielding new hydrofurane-type products. The mechanism of this Si–H bond activation was studied both experimentally and by DFT calculations, and supposedly proceeds in an FLP-type manner.

Graphical abstract: A self-catalyzed reaction of 1,2-dibenzoyl-o-carborane with hydrosilanes – formation of new hydrofuranes

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Publication details

The article was received on 21 Jun 2019, accepted on 06 Aug 2019 and first published on 06 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC04780H
Chem. Commun., 2019, Advance Article

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    A self-catalyzed reaction of 1,2-dibenzoyl-o-carborane with hydrosilanes – formation of new hydrofuranes

    K. Jaiswal, S. Volodarsky, V. Kampel and R. Dobrovetsky, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC04780H

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