Fluorination observed Tc increase of 110 K is challenging the hydrogen–deuterium isotope effect

Yu-Ling Liu; Si-Qi Lu; Yuan-Yuan Tang; Xiao-Gang Chen; Ji-Xing Gao; Hao-Jie Li; Ren-Gen Xiong

doi:10.1039/C9CC04658E

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Fluorination observed T_c increase of 110 K is challenging the hydrogen–deuterium isotope effect†

Yu-Ling Liu,^a Si-Qi Lu,^b Yuan-Yuan Tang,*^a Xiao-Gang Chen,^b Ji-Xing Gao,

^b Hao-Jie Li^b and Ren-Gen Xiong

*^ab

Author affiliations

* Corresponding authors

^a Ordered Matter Science Research Center, Nanchang University, Nanchang 330031, People's Republic of China
E-mail: tangyuanyuan@ncu.edu.cn, xiongrg@seu.edu.cn

^b Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, People's Republic of China

Abstract

The significant T_c enhancement of 110 K in [N-fluoromethyldabconium] triiodide lead caused by the promising design of H/F substitution is the first and unprecedented, opening up an applicable and universal strategy to effectively regulate the T_c working temperature in phase transition materials.

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Article information

DOI: https://doi.org/10.1039/C9CC04658E
Article type: Communication
Submitted: 18 Jun 2019
Accepted: 29 Jul 2019
First published: 29 Jul 2019

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Chem. Commun., 2019,55, 10007-10010

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Fluorination observed T_c increase of 110 K is challenging the hydrogen–deuterium isotope effect

Y. Liu, S. Lu, Y. Tang, X. Chen, J. Gao, H. Li and R. Xiong, Chem. Commun., 2019, 55, 10007 DOI: 10.1039/C9CC04658E

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