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Issue 84, 2019
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Comment on “Exploiting electronic strategies to stabilize a planar tetracoordinate carbon in cyclic aromatic hydrocarbons” by O. Yañez et al., Chem. Commun., 2017, 53, 12112

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Abstract

Unequivocally, the global minimum geometry for C7H2 is the linear triplet ground electronic state of heptatriynylidene (1). However, the entitled article reports that the global minimum geometry for C7H2 is the singlet ground electronic state of 1-(buta-1,3-diynyl)cyclopropenylidene (2). We disagree with this result.

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Publication details

The article was received on 17 Jun 2019, accepted on 30 Sep 2019 and first published on 07 Oct 2019


Article type: Comment
DOI: 10.1039/C9CC04639A
Chem. Commun., 2019,55, 12719-12720

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    Comment on “Exploiting electronic strategies to stabilize a planar tetracoordinate carbon in cyclic aromatic hydrocarbons” by O. Yañez et al., Chem. Commun., 2017, 53, 12112

    V. S. Thimmakondu, Chem. Commun., 2019, 55, 12719
    DOI: 10.1039/C9CC04639A

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