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Blurring the line between addenda and heteroatoms in a giant polyoxotungstotellurite

Abstract

The 3.5 nm-sized polyanion [H4Te(IV)48W(VI)78O372]80–, exhibiting an exceptionally high Te:W ratio, expands the structural role of TeIV ions from classical heterogroups within polyoxotungstate subunits to addenda ions. Investigations on the self-assembly conditions, proceeding in a simple one-pot reaction, point to the pH as one critical factor for circumventing this limitation.

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Publication details

The article was received on 17 Jun 2019, accepted on 14 Aug 2019 and first published on 14 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC04623B
Chem. Commun., 2019, Accepted Manuscript

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    Blurring the line between addenda and heteroatoms in a giant polyoxotungstotellurite

    J. Liu, N. V. Izarova and P. Kögerler, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC04623B

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