Jeong Hwa Song, Dae Won Kim, Dong Won Kang, Woo Ram Lee and Chang Seop Hong
Chem. Commun., 2019,55, 9713-9716
DOI:
10.1039/C9CC04474D,
Communication
Single-crystal-to-single crystal structural conversions occur in a Zn(II) coordination polymer, uniquely induced by fine-tuned relative humidity. Proton conductivity depends on the number of hydrogen bonds in the structures. Slope change in the Arrhenius plot is uncommon among coordination-based conductors and associated with temperature-dependent phase changes.