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Issue 63, 2019
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Mechanistic insights of Cu(ii)-mediated ortho-C–H amination of arenes by capturing fleeting intermediates and theoretical calculations

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Abstract

The capture of reactive intermediates empowers chemists to conjecture the detail of a chemical transformation. Here we explore the mechanism of a C–H amination by intercepting short-lived intermediates in real time using online mass spectrometry. Computational study unravels the favorable pathway of the proposed dual mechanism of the reaction.

Graphical abstract: Mechanistic insights of Cu(ii)-mediated ortho-C–H amination of arenes by capturing fleeting intermediates and theoretical calculations

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Publication details

The article was received on 05 Jun 2019, accepted on 08 Jul 2019 and first published on 08 Jul 2019


Article type: Communication
DOI: 10.1039/C9CC04317A
Chem. Commun., 2019,55, 9359-9362

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    Mechanistic insights of Cu(II)-mediated ortho-C–H amination of arenes by capturing fleeting intermediates and theoretical calculations

    M. Kumar, S. Verma, A. Kumar, P. K. Mishra, R. O. Ramabhadran, S. Banerjee and A. K. Verma, Chem. Commun., 2019, 55, 9359
    DOI: 10.1039/C9CC04317A

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