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Issue 63, 2019
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Mechanistic insights of Cu(ii)-mediated ortho-C–H amination of arenes by capturing fleeting intermediates and theoretical calculations

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Abstract

The capture of reactive intermediates empowers chemists to conjecture the detail of a chemical transformation. Here we explore the mechanism of a C–H amination by intercepting short-lived intermediates in real time using online mass spectrometry. Computational study unravels the favorable pathway of the proposed dual mechanism of the reaction.

Graphical abstract: Mechanistic insights of Cu(ii)-mediated ortho-C–H amination of arenes by capturing fleeting intermediates and theoretical calculations

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Article information


Submitted
05 Jun 2019
Accepted
08 Jul 2019
First published
08 Jul 2019

Chem. Commun., 2019,55, 9359-9362
Article type
Communication

Mechanistic insights of Cu(II)-mediated ortho-C–H amination of arenes by capturing fleeting intermediates and theoretical calculations

M. Kumar, S. Verma, A. Kumar, P. K. Mishra, R. O. Ramabhadran, S. Banerjee and A. K. Verma, Chem. Commun., 2019, 55, 9359
DOI: 10.1039/C9CC04317A

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