New insights into solvent-induced structural changes of 13C labelled metal–organic frameworks by solid state NMR

Marcus Rauche; Sebastian Ehrling; Simon Krause; Irena Senkovska; Stefan Kaskel; Eike Brunner

doi:10.1039/C9CC04298A

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New insights into solvent-induced structural changes of ¹³C labelled metal–organic frameworks by solid state NMR†

Marcus Rauche,‡^a Sebastian Ehrling,‡^b Simon Krause,

§^b Irena Senkovska,^b Stefan Kaskel^b and Eike Brunner

*^a

Author affiliations

* Corresponding authors

^a Chair of Bioanalytical Chemistry, TU Dresden, D-01062 Dresden, Germany
E-mail: eike.brunner@tu-dresden.de

^b Chair of Inorganic Chemistry I, TU Dresden, D-01062 Dresden, Germany

Abstract

Selective ¹³C-labelling of carboxylate carbons in the linker molecules of flexible metal–organic frameworks (MOFs) makes solid-state NMR spectroscopy very powerful to investigate solvent-induced local structural changes as demonstrated by ¹³C and ¹H NMR spectroscopy on the pillared layer MOF DUT-8(Ni). Selective identification of polar solvent–node interactions becomes feasible.

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Article information

DOI: https://doi.org/10.1039/C9CC04298A
Article type: Communication
Submitted: 04 Jun 2019
Accepted: 08 Jul 2019
First published: 08 Jul 2019
This article is Open Access

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Chem. Commun., 2019,55, 9140-9143

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New insights into solvent-induced structural changes of ¹³C labelled metal–organic frameworks by solid state NMR

M. Rauche, S. Ehrling, S. Krause, I. Senkovska, S. Kaskel and E. Brunner, Chem. Commun., 2019, 55, 9140 DOI: 10.1039/C9CC04298A

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