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Issue 54, 2019
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2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant

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Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Graphical abstract: 2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant

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Supplementary files

Article information


Submitted
31 May 2019
Accepted
07 Jun 2019
First published
07 Jun 2019

Chem. Commun., 2019,55, 7760-7763
Article type
Communication
Author version available

2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(V) oxidant

M. S. Yusubov, N. S. Soldatova, P. S. Postnikov, R. R. Valiev, A. Yoshimura, T. Wirth, V. N. Nemykin and V. V. Zhdankin, Chem. Commun., 2019, 55, 7760
DOI: 10.1039/C9CC04203B

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