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Issue 64, 2019
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Photocatalytic hydrogen evolution on Si photocathodes modified with bis(thiosemicarbazonato)nickel(ii)/Nafion

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Abstract

The molecular catalyst diacetyl-bis(N-4-methyl-3-thiosemi-carbazonato)nickel(II) (NiATSM) was integrated with Si for light-driven hydrogen evolution from water. Compared to an equivalent loading of Ni metal, the NiATSM/p-Si electrode performed better. Durability of the surface-bound catalyst under operation in acid was achieved without covalent attachment by using Nafion binding.

Graphical abstract: Photocatalytic hydrogen evolution on Si photocathodes modified with bis(thiosemicarbazonato)nickel(ii)/Nafion

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Article information


Submitted
28 May 2019
Accepted
15 Jul 2019
First published
15 Jul 2019

Chem. Commun., 2019,55, 9440-9443
Article type
Communication

Photocatalytic hydrogen evolution on Si photocathodes modified with bis(thiosemicarbazonato)nickel(II)/Nafion

S. Gulati, O. Hietsoi, C. A. Calvary, J. M. Strain, S. Pishgar, H. C. Brun, C. A. Grapperhaus, R. M. Buchanan and J. M. Spurgeon, Chem. Commun., 2019, 55, 9440
DOI: 10.1039/C9CC04117F

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