Issue 57, 2019

Precise regulation of the selectivity of supported nano-Pd catalysts using polysiloxane coatings with tunable surface wettability

Abstract

A facile method was developed for surface modification of supported nano-Pd catalysts with tailorable wettability. The obtained Pd/TiO2@POS catalytic materials could be used in the controllable synthesis of styrene and ethylbenzene obtained from hydrogenation of phenylacetylene and the selective synthesis of imine and N-methylanilines via a reductive amination reaction. The precise modification of the hydrophilicity/hydrophobicity of the catalyst surface is crucial to realize this targeted transformation.

Graphical abstract: Precise regulation of the selectivity of supported nano-Pd catalysts using polysiloxane coatings with tunable surface wettability

Supplementary files

Article information

Article type
Communication
Submitted
16 May 2019
Accepted
20 Jun 2019
First published
20 Jun 2019

Chem. Commun., 2019,55, 8305-8308

Precise regulation of the selectivity of supported nano-Pd catalysts using polysiloxane coatings with tunable surface wettability

H. Wang, Z. Gao, X. Wang, R. Wei, J. Zhang and F. Shi, Chem. Commun., 2019, 55, 8305 DOI: 10.1039/C9CC03800K

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