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Issue 60, 2019
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Multi-component heteroarene couplings via polarity-reversed radical cascades

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Abstract

A multi-component radical addition strategy enables difunctionalization of alkenes with heteroarenes and a variety of radical precursors, including N3, P(O)R2, and CF3. This unified approach for coupling diverse classes of electrophilic radicals and heteroarenes to vinyl ethers allows for direct, vicinal C–C as well as C–N, C–P, and C–Rf bond formation.

Graphical abstract: Multi-component heteroarene couplings via polarity-reversed radical cascades

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Supplementary files

Article information


Submitted
07 May 2019
Accepted
21 May 2019
First published
21 May 2019

Chem. Commun., 2019,55, 8820-8823
Article type
Communication
Author version available

Multi-component heteroarene couplings via polarity-reversed radical cascades

J. M. Lear, J. Q. Buquoi, X. Gu, K. Pan, D. N. Mustafa and D. A. Nagib, Chem. Commun., 2019, 55, 8820 DOI: 10.1039/C9CC03498F

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