Issue 69, 2019

A robust cage-based framework for the highly selective purification of natural gas

Abstract

A robust microporous material (FJI-H19), which is constructed from distorted cuboctahedral cages and distorted octahedral cages, has been successfully synthesized. FJI-H19 possesses good thermal and water stability as well as highly selective adsorption of C3 and C4 hydrocarbons over CH4 under ambient conditions. More importantly, the high selectivities for the separation of CH4/C3 or C4 mixtures (85/15) have not only been estimated by ideal adsorbed solution theory (IAST) but also definitely confirmed by breakthrough experiments.

Graphical abstract: A robust cage-based framework for the highly selective purification of natural gas

Supplementary files

Article information

Article type
Communication
Submitted
01 May 2019
Accepted
26 Jul 2019
First published
30 Jul 2019

Chem. Commun., 2019,55, 10257-10260

A robust cage-based framework for the highly selective purification of natural gas

F. Hu, P. Huang, Z. Di, M. Wu, F. Jiang and M. Hong, Chem. Commun., 2019, 55, 10257 DOI: 10.1039/C9CC03354H

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