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Issue 69, 2019
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A robust cage-based framework for the highly selective purification of natural gas

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Abstract

A robust microporous material (FJI-H19), which is constructed from distorted cuboctahedral cages and distorted octahedral cages, has been successfully synthesized. FJI-H19 possesses good thermal and water stability as well as highly selective adsorption of C3 and C4 hydrocarbons over CH4 under ambient conditions. More importantly, the high selectivities for the separation of CH4/C3 or C4 mixtures (85/15) have not only been estimated by ideal adsorbed solution theory (IAST) but also definitely confirmed by breakthrough experiments.

Graphical abstract: A robust cage-based framework for the highly selective purification of natural gas

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Publication details

The article was received on 01 May 2019, accepted on 26 Jul 2019 and first published on 30 Jul 2019


Article type: Communication
DOI: 10.1039/C9CC03354H
Chem. Commun., 2019,55, 10257-10260

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    A robust cage-based framework for the highly selective purification of natural gas

    F. Hu, P. Huang, Z. Di, M. Wu, F. Jiang and M. Hong, Chem. Commun., 2019, 55, 10257
    DOI: 10.1039/C9CC03354H

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