Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 22nd May 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.



[Bi7M3(CO)3]2- (M = Co, Rh): A New Prototype of 10-vertex Deltahedral Hybrids From Unprecedented Polycyclic η5−coordination addition of Bi73- and trimetallic fragments†

Abstract

Redox reactions of K5Bi4 and CpCo(CO)2/Rh(CO)2(acac) (acac = acetylacetonate) in ethylenediamine (en) yielded the first Bi73- adducts [Bi7M3(CO)3]2- (M = Co, 1a; Rh, 2a) having a new prototype of 10-vertex deltahedral structure resulting from the unprecedented polycyclic η5−coordination addition of Bi73- cage and three MCO+ fragments.

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Apr 2019, accepted on 10 May 2019 and first published on 14 May 2019


Article type: Communication
DOI: 10.1039/C9CC03079D
Chem. Commun., 2019, Accepted Manuscript

  •   Request permissions

    [Bi7M3(CO)3]2- (M = Co, Rh): A New Prototype of 10-vertex Deltahedral Hybrids From Unprecedented Polycyclic η5−coordination addition of Bi73- and trimetallic fragments†

    Z. Li, O. Dan and L. Xu, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC03079D

Search articles by author

Spotlight

Advertisements