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Issue 60, 2019
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Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(i) metal-only Lewis pair

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Abstract

Metal-only Lewis pairs made of Pt(0)/Ag(I) combinations have been previously reported, but their cooperative reactivity remains unexplored. Here we demonstrate that these systems are capable of synergistically activating a wide variety of X–H (X = H, C, O, N) bonds, including those in dihydrogen, alkynes, water and ammonia.

Graphical abstract: Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(i) metal-only Lewis pair

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Publication details

The article was received on 17 Apr 2019, accepted on 17 May 2019 and first published on 17 May 2019


Article type: Communication
DOI: 10.1039/C9CC03008E
Chem. Commun., 2019,55, 8812-8815
  • Open access: Creative Commons BY-NC license
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    Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(I) metal-only Lewis pair

    N. Hidalgo, C. Maya and J. Campos, Chem. Commun., 2019, 55, 8812
    DOI: 10.1039/C9CC03008E

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