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Cooperative Activation of X-H (X = H, C, O, N) Bonds by a Pt(0)/Ag(I) Metal-Only Lewis Pair

Abstract

Metal-only Lewis pairs made of Pt(I)/Ag(0) combinations have been previously reported, but their cooperative reactivity remains unexplored. Here we demonstrate that these systems are capable of synergistically activating a wide variety of X-H (X = H, C, O, N) bonds, including those in dihydrogen, alkynes, water and ammonia.

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Publication details

The article was received on 17 Apr 2019, accepted on 17 May 2019 and first published on 17 May 2019


Article type: Communication
DOI: 10.1039/C9CC03008E
Chem. Commun., 2019, Accepted Manuscript
  • Open access: Creative Commons BY-NC license
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    Cooperative Activation of X-H (X = H, C, O, N) Bonds by a Pt(0)/Ag(I) Metal-Only Lewis Pair

    N. Hidalgo, C. Maya and J. Campos, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC03008E

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