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Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates

Abstract

Altering the organic spacers in hybrid complexes of polyoxotungstates and long-chain α,ω-alkyldiphosphonates (Ln), by a single CH2 group (e.g. L6 vs L5), can steer the self-assembly processes into different paths. Even homologous hybrids of L5 and L4 have seen the spin ground states switch from S = 0 to S = 9 upon shortening the chain length (L5 vs L4).

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Publication details

The article was received on 12 Apr 2019, accepted on 13 May 2019 and first published on 13 May 2019


Article type: Communication
DOI: 10.1039/C9CC02854D
Chem. Commun., 2019, Accepted Manuscript

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    Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates

    Z. Liu, W. Wang, J. Tang, W. Li, W. Yin and X. Fang, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC02854D

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