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Issue 60, 2019
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Tuning of the flexibility in metal–organic frameworks based on pendant arm macrocycles

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Abstract

An isostructural series of flexible metal–organic frameworks based on macrocycles having diverse pendant arms was developed to tune flexibility depending on functional groups. The pendant arms directing into the pores were found to play a key role in imparting different gate-opening behaviours in the threshold pressure and sorption capacity upon interaction with guest molecules.

Graphical abstract: Tuning of the flexibility in metal–organic frameworks based on pendant arm macrocycles

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Article information


Submitted
11 Apr 2019
Accepted
24 May 2019
First published
24 May 2019

Chem. Commun., 2019,55, 8832-8835
Article type
Communication

Tuning of the flexibility in metal–organic frameworks based on pendant arm macrocycles

S. Jeoung, S. Lee, J. H. Lee, S. Lee, W. Choe, D. Moon and H. R. Moon, Chem. Commun., 2019, 55, 8832 DOI: 10.1039/C9CC02819F

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