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“Normal” and “reverse” spin crossover induced by two different structural events in iron(II) coordination polymer

Abstract

In [Fe(ebbtr)2(CH3CN)2](CF3SO3)2·4CH3CN spin crossover is associated with occurrence of “normal” and “reverse” hysteresis loops separated by area of stable HS form. It results from: trans-trans↔gauche-trans conformational changes of ebbtr molecules and anion reorientation which occur in different ways during cooling and during heating.

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Publication details

The article was received on 09 Apr 2019, accepted on 14 May 2019 and first published on 14 May 2019


Article type: Communication
DOI: 10.1039/C9CC02755F
Chem. Commun., 2019, Accepted Manuscript

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    “Normal” and “reverse” spin crossover induced by two different structural events in iron(II) coordination polymer

    M. D. Weselski, M. Książek, P. Mess, J. Kusz and R. Bronisz, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC02755F

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