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Issue 49, 2019
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“Normal” and “reverse” spin crossover induced by two different structural events in iron(II) coordination polymer

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Abstract

In [Fe(ebbtr)2(CH3CN)2](CF3SO3)2·4CH3CN spin crossover is associated with the occurrence of “normal” and “reverse” hysteresis loops separated by a region of stable HS form. This results from transtransgauchetrans conformational changes of ebbtr molecules and anion reorientation, which occur in different ways during cooling and during heating.

Graphical abstract: “Normal” and “reverse” spin crossover induced by two different structural events in iron(ii) coordination polymer

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Publication details

The article was received on 09 Apr 2019, accepted on 14 May 2019 and first published on 14 May 2019


Article type: Communication
DOI: 10.1039/C9CC02755F
Chem. Commun., 2019,55, 7033-7036

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    “Normal” and “reverse” spin crossover induced by two different structural events in iron(II) coordination polymer

    M. Weselski, M. Książek, P. Mess, J. Kusz and R. Bronisz, Chem. Commun., 2019, 55, 7033
    DOI: 10.1039/C9CC02755F

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