Issue 41, 2019
From the journal:

Chemical Communications

Pressure-dependent guest binding and release on a supramolecular polymer†

Shumpei Yonezawa,a   Ramarani Sethy,a   Gaku Fukuhara, ORCID logo bc   Tsuyoshi Kawai ORCID logo *a  and  Takuya Nakashima ORCID logo *a  

* Corresponding authors

a Division of Materials Science, Nara Institute of Science and Technology, Ikoma, Nara 630-0192, Japan
E-mail: tkawai@ms.naist.jp, ntaku@ms.naist.jp

b Department of Chemistry, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8551, Japan

c PRESTO, JST, Honcho 4-1-8, Kawaguchi, Saitama 332-0012, Japan

Abstract

Chiral guest binding on a self-assembly of a bichromophoric naphthalenediimide (NDI) derivative is modulated in response to pressure. The intermolecular packing in the supramolecular polymer is strengthened at high pressure, compressing the binding pockets and discharging the guest molecules.

Graphical abstract: Pressure-dependent guest binding and release on a supramolecular polymer

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Article information

DOI
https://doi.org/10.1039/C9CC02696G
Article type
Communication
Submitted
08 Apr 2019
Accepted
24 Apr 2019
First published
24 Apr 2019

Chem. Commun., 2019,55, 5793-5796

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Pressure-dependent guest binding and release on a supramolecular polymer

S. Yonezawa, R. Sethy, G. Fukuhara, T. Kawai and T. Nakashima, Chem. Commun., 2019, 55, 5793 DOI: 10.1039/C9CC02696G

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