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Issue 44, 2019
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Regioselective installation of fluorosulfate (–OSO2F) functionality into aromatic C(sp2)–H bonds for the construction of para-amino-arylfluorosulfates

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Abstract

The construction of para-amino-arylfluorosulfates was achieved through installation of fluorosulfate (–OSO2F) functionality into aromatic C(sp2)–H bonds by the reaction of N-arylhydroxylamine with sulfuryl fluoride (SO2F2). This method provides a mild process for the preparation of broadly applicable fluorosulfate moieties without the requirement of phenols or transition metals.

Graphical abstract: Regioselective installation of fluorosulfate (–OSO2F) functionality into aromatic C(sp2)–H bonds for the construction of para-amino-arylfluorosulfates

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Article information


Submitted
05 Apr 2019
Accepted
02 May 2019
First published
02 May 2019

Chem. Commun., 2019,55, 6273-6276
Article type
Communication

Regioselective installation of fluorosulfate (–OSO2F) functionality into aromatic C(sp2)–H bonds for the construction of para-amino-arylfluorosulfates

W. Fang, G. Zha, C. Zhao and H. Qin, Chem. Commun., 2019, 55, 6273
DOI: 10.1039/C9CC02659B

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