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Correlating blocking temperatures with relaxation mechanisms in monometallic single-molecule magnets with high energy barriers (Ueff > 600 K)

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Abstract

We report an empirical correlation between the blocking temperature of large energy barrier SMMs and the relaxation time at the point where the Raman and Orbach relaxation mechanisms have the same rate; this supports the idea that the ability to retain magnetisation is controlled by the Raman relaxation process in these materials.

Graphical abstract: Correlating blocking temperatures with relaxation mechanisms in monometallic single-molecule magnets with high energy barriers (Ueff > 600 K)

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Publication details

The article was received on 28 Mar 2019, accepted on 26 Apr 2019 and first published on 29 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC02421B
Chem. Commun., 2019, Advance Article

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    Correlating blocking temperatures with relaxation mechanisms in monometallic single-molecule magnets with high energy barriers (Ueff > 600 K)

    M. J. Giansiracusa, A. K. Kostopoulos, D. Collison, R. E. P. Winpenny and N. F. Chilton, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC02421B

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