Issue 47, 2019
From the journal:

Chemical Communications

Ti cluster-alkylated hydrophobic MOFs for photocatalytic production of hydrogen peroxide in two-phase systems†

Yudai Kawase,a   Yusuke Isaka,a   Yasutaka Kuwahara, ORCID logo ab   Kohsuke Mori ORCID logo abc  and  Hiromi Yamashita ORCID logo *ab  

* Corresponding authors

a Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: yamashita@mat.eng.osaka-u.ac.jp

b Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Katsura, Kyoto 615-8520, Japan

c JST, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

Abstract

A hydrophobic MOF, OPA/MIL-125-NH2, whose Ti cluster was alkylated with octadecylphosphonic acid (OPA), was found to enhance photocatalytic H2O2 production in a two-phase system. Its activity exceeded that of linker-alkylated MIL-125-NH2. OPA/MIL-125-NH2 was modified on its outermost surface, which resulted in the activity enhancement while preserving the inner pores of the inherent MOF.

Graphical abstract: Ti cluster-alkylated hydrophobic MOFs for photocatalytic production of hydrogen peroxide in two-phase systems

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Article information

DOI
https://doi.org/10.1039/C9CC02380A
Article type
Communication
Submitted
27 Mar 2019
Accepted
14 May 2019
First published
14 May 2019

Chem. Commun., 2019,55, 6743-6746

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Ti cluster-alkylated hydrophobic MOFs for photocatalytic production of hydrogen peroxide in two-phase systems

Y. Kawase, Y. Isaka, Y. Kuwahara, K. Mori and H. Yamashita, Chem. Commun., 2019, 55, 6743 DOI: 10.1039/C9CC02380A

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