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Ti cluster-alkylated hydrophobic MOFs for photocatalytic production of hydrogen peroxide in two-phase systems

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Abstract

A hydrophobic MOF, OPA/MIL-125-NH2, whose Ti cluster was alkylated with octadecylphosphonic acid (OPA), was found to enhance photocatalytic H2O2 production in a two-phase system. Its activity exceeded that of linker-alkylated MIL-125-NH2. OPA/MIL-125-NH2 was modified on its outermost surface, which resulted in the activity enhancement while preserving the inner pores of the inherent MOF.

Graphical abstract: Ti cluster-alkylated hydrophobic MOFs for photocatalytic production of hydrogen peroxide in two-phase systems

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Publication details

The article was received on 27 Mar 2019, accepted on 14 May 2019 and first published on 14 May 2019


Article type: Communication
DOI: 10.1039/C9CC02380A
Chem. Commun., 2019, Advance Article

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    Ti cluster-alkylated hydrophobic MOFs for photocatalytic production of hydrogen peroxide in two-phase systems

    Y. Kawase, Y. Isaka, Y. Kuwahara, K. Mori and H. Yamashita, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC02380A

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