Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes†
Abstract
All-cis-1,3,5-triethynyl-1,3,5-triorganyl-1,3,5-trisilacyclohexanes (organyl R = Me, Ph) offer flexible scaffolds with three concordantly oriented ethynyl groups. Lithiation with n-BuLi affords the dimeric {[CH2Si(R)(C2Li)]3(THF)3}2 with a drum-like structure in high yields. They can be transformed into other trinuclear organometallic derivatives like the trimercury cage species [CH2Si(R)C2HgC2(R)SiCH2]3.