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Fluorinated porous molecular crystals: vapor-triggered on–off switching of luminescence and porosity

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Abstract

A platinum diiodide complex with 9-pentafluorophenyl-9-arsafluorene formed a porous molecular crystal (PMC) or a non-porous molecular crystal (n-PMC), depending on the recrystallization solvents. Vapor exposure can cause reversible crystal-to-crystal transition between the PMC and the n-PMC. The PMC exhibits open–close switching of porosity as well as on–off switching of luminescence.

Graphical abstract: Fluorinated porous molecular crystals: vapor-triggered on–off switching of luminescence and porosity

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Publication details

The article was received on 25 Mar 2019, accepted on 09 May 2019 and first published on 09 May 2019


Article type: Communication
DOI: 10.1039/C9CC02309G
Chem. Commun., 2019, Advance Article

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    Fluorinated porous molecular crystals: vapor-triggered on–off switching of luminescence and porosity

    H. Sasaki, H. Imoto, T. Kitao, T. Uemura, T. Yumura and K. Naka, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC02309G

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