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Dual dynamic chirality generated in the assembly of three achiral rods through the three-fold twisting of a macrocycle

Abstract

We demonstrated dynamic chirality based on assemblies of three achiral rods with a twisted macrocycle. The three-fold twisting of a macrocycle can lead to two different chiral forms with C2- or D3-symmetry. Through a transmission of chirality to each dynamic chiral form, a helical-sense preference was successfully induced.

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Publication details

The article was received on 20 Mar 2019, accepted on 16 Apr 2019 and first published on 16 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC02226K
Citation: Chem. Commun., 2019, Accepted Manuscript

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    Dual dynamic chirality generated in the assembly of three achiral rods through the three-fold twisting of a macrocycle

    R. Katoono, K. Sakamoto and T. Suzuki, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC02226K

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