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Pd-catalyzed synthesis of α,β-unsaturated ketones by carbonylation of vinyl triflates and nonaflates

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Abstract

A general and highly chemoselective Pd-catalyzed protocol for the synthesis of α,β-unsaturated ketones by carbonylation of vinyl triflates and nonaflates is presented. Applying the specific monophosphine ligand cataCXium® A, the synthesis of various vinyl ketones as well as carbonylated natural product derivatives proceeds in good yields.

Graphical abstract: Pd-catalyzed synthesis of α,β-unsaturated ketones by carbonylation of vinyl triflates and nonaflates

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Publication details

The article was received on 20 Mar 2019, accepted on 24 Apr 2019 and first published on 24 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC02210D
Chem. Commun., 2019, Advance Article

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    Pd-catalyzed synthesis of α,β-unsaturated ketones by carbonylation of vinyl triflates and nonaflates

    S. Zhang, H. Neumann and M. Beller, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC02210D

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