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Crystal melting and glass formation in copper thiocyanate based coordination polymers

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Abstract

Crystal melting and glass formation of coordination polymers (CPs) and metal–organic frameworks (MOFs) are rare thermal events. To expand the library of melting CP/MOFs, we utilized anti-crystal engineering in ionic liquids to construct CPs. A combination of Cu+ and 4,4′-bipyridin-1-ium derivatives afforded four melting CPs showing stable liquid and glassy states.

Graphical abstract: Crystal melting and glass formation in copper thiocyanate based coordination polymers

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Publication details

The article was received on 19 Mar 2019, accepted on 10 Apr 2019 and first published on 10 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC02172H
Citation: Chem. Commun., 2019, Advance Article

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    Crystal melting and glass formation in copper thiocyanate based coordination polymers

    S. S. Nagarkar, H. Kurasho, N. T. Duong, Y. Nishiyama, S. Kitagawa and S. Horike, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC02172H

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