[Ba13Sb36Cl34O54]8−: high-nuclearity cluster for the assembly of nanocluster-based compounds†
Abstract
Herein, we report two nanocluster-based compounds built on an unprecedented cluster [Ba13Sb36Cl34O54]8−, which represents the first example of a discrete alkaline earth (AE)-containing oxochloride cluster and the largest Sb-based oxohalide cluster to date; the proton-conducting property of the compounds was investigated.