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Issue 41, 2019
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Phase transition of spiropyrans: impact of isomerization dynamics at high temperatures

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Abstract

Isomerization behaviors of spiropyran derivatives in neat condensed phase were studied to understand their unusual phase transitions including cold-crystallization after extreme supercooling down to −50 °C. Compounds with different functional groups were compared, and the equilibrium between isomers at high temperatures was found to determine phase transitions.

Graphical abstract: Phase transition of spiropyrans: impact of isomerization dynamics at high temperatures

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Article information


Submitted
18 Mar 2019
Accepted
24 Apr 2019
First published
24 Apr 2019

Chem. Commun., 2019,55, 5813-5816
Article type
Communication
Author version available

Phase transition of spiropyrans: impact of isomerization dynamics at high temperatures

M. A. Gerkman, S. Yuan, P. Duan, J. Taufan, K. Schmidt-Rohr and G. G. D. Han, Chem. Commun., 2019, 55, 5813
DOI: 10.1039/C9CC02141H

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