Issue 35, 2019
From the journal:

Chemical Communications

Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages†

Liang Liang,‡b   Dong Luo, ORCID logo ‡a   Tao Zuo,a   Xiao-Ping Zhou ORCID logo *a  and  Dan Li ORCID logo *a  

* Corresponding authors

a College of Chemistry and Materials Science, Jinan University, Guangzhou, Guangdong 510632, P. R. China
E-mail: zhouxp@jnu.edu.cn, danli@jnu.edu.cn

b Department of Chemistry, Shantou University, Shantou, Guangdong 515063, P. R. China

Abstract

A series of cubic cobalt-imidazolate cages have been successfully synthesized via subcomponent self-assembly in different solvents under solvothermal conditions. The homovalent CoII and mixed-valence CoIII,II-imidazolate cages are assembled with control over the mixed solvent ratio of N,N-diethylformamide/ethanol, respectively.

Graphical abstract: Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages

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Article information

DOI
https://doi.org/10.1039/C9CC02083G
Article type
Communication
Submitted
14 Mar 2019
Accepted
01 Apr 2019
First published
02 Apr 2019

Chem. Commun., 2019,55, 5103-5106

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Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages

L. Liang, D. Luo, T. Zuo, X. Zhou and D. Li, Chem. Commun., 2019, 55, 5103 DOI: 10.1039/C9CC02083G

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