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Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages

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Abstract

A series of cubic cobalt-imidazolate cages have been successfully synthesized via subcomponent self-assembly in different solvents under solvothermal conditions. The homovalent CoII and mixed-valence CoIII,II-imidazolate cages are assembled with control over the mixed solvent ratio of N,N-diethylformamide/ethanol, respectively.

Graphical abstract: Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages

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Publication details

The article was received on 14 Mar 2019, accepted on 01 Apr 2019 and first published on 02 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC02083G
Citation: Chem. Commun., 2019, Advance Article

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    Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages

    L. Liang, D. Luo, T. Zuo, X. Zhou and D. Li, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC02083G

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