Issue 43, 2019

Planarization of tetracarboxamides: tuning the self-assembly of polycyclic aromatic hydrocarbons

Abstract

The geometry-dependent self-assembling features of two PAHs, 1 and 2, are reported. The more planar 1 forms H-type supramolecular polymers, in a highly cooperative fashion, by a combination of H-bonding and π-stacking, with rod-like morphology. However, the highly distorted 2 interacts only by means of H-bonding with no contact between the aromatic units, yielding lamellar supramolecular structures.

Graphical abstract: Planarization of tetracarboxamides: tuning the self-assembly of polycyclic aromatic hydrocarbons

Supplementary files

Article information

Article type
Communication
Submitted
12 Mar 2019
Accepted
26 Apr 2019
First published
29 Apr 2019

Chem. Commun., 2019,55, 6070-6073

Planarization of tetracarboxamides: tuning the self-assembly of polycyclic aromatic hydrocarbons

Y. Dorca, C. Naranjo, P. Delgado-Martínez, R. Gómez and L. Sánchez, Chem. Commun., 2019, 55, 6070 DOI: 10.1039/C9CC02000D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements