Cu-Catalyzed atom transfer radical addition reactions of alkenes with α-bromoacetonitrile

Weiya Pu; Dani Sun; Wanyue Fan; Wenwen Pan; Qinghui Chai; Xiaoxing Wang; Yunhe Lv

doi:10.1039/C9CC01988J

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Cu-Catalyzed atom transfer radical addition reactions of alkenes with α-bromoacetonitrile†

Weiya Pu,^a Dani Sun,^a Wanyue Fan,^a Wenwen Pan,^a Qinghui Chai,^a Xiaoxing Wang^a and Yunhe Lv

*^ab

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* Corresponding authors

^a College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, P. R. China
E-mail: lvyunhe0217@163.com

^b Jilin Provincial Key Laboratory of Organic Functional Molecular Design & Synthesis, Northeast Normal University, Changchun 130024, P. R. China
E-mail: luyh086@nenu.edu.cn

Abstract

A practical, simple, and efficient copper-catalyzed atom transfer radical addition reaction of alkenes with α-bromoacetonitrile is realized. With this methodology, various γ-bromonitriles and β,γ-unsaturated nitriles were efficiently constructed.

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Article information

DOI: https://doi.org/10.1039/C9CC01988J
Article type: Communication
Submitted: 12 Mar 2019
Accepted: 28 Mar 2019
First published: 28 Mar 2019

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Chem. Commun., 2019,55, 4821-4824

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Cu-Catalyzed atom transfer radical addition reactions of alkenes with α-bromoacetonitrile

W. Pu, D. Sun, W. Fan, W. Pan, Q. Chai, X. Wang and Y. Lv, Chem. Commun., 2019, 55, 4821 DOI: 10.1039/C9CC01988J

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Chemical Communications

Cu-Catalyzed atom transfer radical addition reactions of alkenes with α-bromoacetonitrile†

Abstract

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Cu-Catalyzed atom transfer radical addition reactions of alkenes with α-bromoacetonitrile

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