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A General and Practical Ni-Catalyzed C-H Perfluoroalkylation of (Hetero)Arenes

Abstract

A direct perfluoroalkylation of (hetero)arenes using the air- and moisture-stable complex (dppf)Ni(o-tol)Cl was developed (23 examples). The novel procedure allows for the synthesis of various fluorinated products and tolerates sensitive functional groups including aldehydes, free amino groups and several heterocycles.

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Publication details

The article was received on 12 Mar 2019, accepted on 14 May 2019 and first published on 14 May 2019


Article type: Communication
DOI: 10.1039/C9CC01971E
Chem. Commun., 2019, Accepted Manuscript

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    A General and Practical Ni-Catalyzed C-H Perfluoroalkylation of (Hetero)Arenes

    S. Zhang, N. Rotta-Loria, F. Weniger, J. Rabeah, H. Neumann, C. Taeschler and M. Beller, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC01971E

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