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Hydrogen Bonding between Hydroxylic Donors and MLCT-Excited Ru(bpy)2(bpz)2+ Complex: Implications for Photoinduced Electron-Proton Transfer

Abstract

The equilibrium constants of hydrogen bonding (HB) between hydroxylic donors, ROH, and MLCT-excited Ru(bpy)2(bpz)2+ complex, 1(T) correlate with ROH empirical HB acidities, which is used for evaluating the unimolecular rate constants of concerted electron-proton transfer within the H-bonded Phenol-1(T) exciplexes.

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Publication details

The article was received on 08 Mar 2019, accepted on 16 Apr 2019 and first published on 16 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC01896D
Citation: Chem. Commun., 2019, Accepted Manuscript

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    Hydrogen Bonding between Hydroxylic Donors and MLCT-Excited Ru(bpy)2(bpz)2+ Complex: Implications for Photoinduced Electron-Proton Transfer

    S. Lymar, G. Manbeck and D. Polyansky, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC01896D

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