A stable Cerberus tris(maloNHC) and its coinage metal complexes

Reagan Hooper; Alexander Mason; Maleek Montgomery; Braden Clinebell; Ryan Gaynor; Colin McMillen; Daniela Tapu

doi:10.1039/C9CC01892A

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A stable Cerberus tris(maloNHC) and its coinage metal complexes†

Reagan Hooper,^a Alexander Mason,^a Maleek Montgomery,^a Braden Clinebell,^a Ryan Gaynor,^a Colin McMillen

^b and Daniela Tapu

*^a

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* Corresponding authors

^a Department of Chemistry and Biochemistry, Kennesaw State University, 370 Paulding Avenue NW, Kennesaw, GA, USA
E-mail: dtapu@kennesaw.edu
Fax: +1-470-578-9137
Tel: +1-470-578-2259

^b X-ray Crystallography Laboratory, Department of Chemistry, Clemson University, Clemson, SC, USA

Abstract

The first trisanionic Cerberus-type maloNHC has been generated and coordinated to two different coinage metals (Au(I) and Ag(I)). The resulting triszwitterionic metal complexes have been characterized by NMR spectroscopy, elemental analysis, and X-ray crystallography. The molecular structures of the new metal complexes reveal an average Au⋯Au and Ag⋯Ag separation of 20.89 and 21.03 Å respectively, the longest distances reported to date for any related Cerberus-type NHCs.

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DOI: https://doi.org/10.1039/C9CC01892A
Article type: Communication
Submitted: 08 Mar 2019
Accepted: 26 Apr 2019
First published: 30 Apr 2019

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Chem. Commun., 2019,55, 5942-5945

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A stable Cerberus tris(maloNHC) and its coinage metal complexes

R. Hooper, A. Mason, M. Montgomery, B. Clinebell, R. Gaynor, C. McMillen and D. Tapu, Chem. Commun., 2019, 55, 5942 DOI: 10.1039/C9CC01892A

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Chemical Communications

A stable Cerberus tris(maloNHC) and its coinage metal complexes†

Abstract

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A stable Cerberus tris(maloNHC) and its coinage metal complexes

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