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Co-Fe Prussian blue analogue for efficient Fenton-like catalysis: the effect of high-spin cobalt

Abstract

we first report the high spin Co-Fe Prussian blue analogue (Co-Fe PBA) as highly efficient Fenton-like catalyst for sulfate radical (SO4•-) production. Our experiments and density functional theory (DFT) calculations show that the largely elongated SO4-OH bond length, strengthened adsorption and facilitated electron transfer for peroxymonosulfate (PMS) activation catalyzed by high-spin (HS) CoII are the main factors for the excellent activity.

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Publication details

The article was received on 07 Mar 2019, accepted on 14 May 2019 and first published on 14 May 2019


Article type: Communication
DOI: 10.1039/C9CC01872G
Chem. Commun., 2019, Accepted Manuscript

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    Co-Fe Prussian blue analogue for efficient Fenton-like catalysis: the effect of high-spin cobalt

    C. Zhao, B. Liu, X. Li, K. Zhu, R. Hu, Z. Ao and J. Wang, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC01872G

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