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BiCl3-Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF2PO(OEt)2 reagent

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Abstract

A transition metal-free approach was developed for the direct difunctionalization of disubstituted alkynes and terminal alkenes with concomitant formation of C–SCF2PO(OEt)2 and C–Cl bonds. The BiCl3-mediated reaction offered access to high value-added functionalized scaffolds in a single operation under mild conditions. Extension to SCF2PO(OEt)2-containing alkynes was also studied.

Graphical abstract: BiCl3-Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF2PO(OEt)2 reagent

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Publication details

The article was received on 06 Mar 2019, accepted on 25 Mar 2019 and first published on 25 Mar 2019


Article type: Communication
DOI: 10.1039/C9CC01851D
Citation: Chem. Commun., 2019, Advance Article

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    BiCl3-Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF2PO(OEt)2 reagent

    J. Wang, H. Xiong, E. Petit, L. Bailly, X. Pannecoucke, T. Poisson and T. Besset, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC01851D

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