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Issue 60, 2019

BiCl3-Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF2PO(OEt)2 reagent

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Abstract

A transition metal-free approach was developed for the direct difunctionalization of disubstituted alkynes and terminal alkenes with concomitant formation of C–SCF2PO(OEt)2 and C–Cl bonds. The BiCl3-mediated reaction offered access to high value-added functionalized scaffolds in a single operation under mild conditions. Extension to SCF2PO(OEt)2-containing alkynes was also studied.

Graphical abstract: BiCl3-Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF2PO(OEt)2 reagent

Supplementary files

Article information


Submitted
06 Mar 2019
Accepted
25 Mar 2019
First published
25 Mar 2019

Chem. Commun., 2019,55, 8784-8787
Article type
Communication

BiCl3-Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF2PO(OEt)2 reagent

J. Wang, H. Xiong, E. Petit, L. Bailly, X. Pannecoucke, T. Poisson and T. Besset, Chem. Commun., 2019, 55, 8784 DOI: 10.1039/C9CC01851D

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