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Issue 33, 2019
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Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids

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Abstract

The first rhodium-containing oxide-hydride phases, LaSrCo0.5Rh0.5O3H and La0.5Sr1.5Mn0.5Rh0.5O3H, have been prepared via topochemical anion exchange. This clearly demonstrates the ability of rhodium, a late 4d transition metal, to kinetically stabilize oxide-hydride lattices, reinforcing the paradigm of covalent stabilization of transition-metal oxide-hydride phases.

Graphical abstract: Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids

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Publication details

The article was received on 04 Mar 2019, accepted on 01 Apr 2019 and first published on 01 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC01768B
Citation: Chem. Commun., 2019,55, 4861-4864

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    Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids

    L. Jin and M. A. Hayward, Chem. Commun., 2019, 55, 4861
    DOI: 10.1039/C9CC01768B

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