Issue 39, 2019

Synthesis of N-unsubstituted cycloalkylimines containing a 4 to 8-membered ring

Abstract

Primary cycloalkylimines with a 4 to 8-membered ring were synthesized by dehydrocyanation of the corresponding α-aminonitriles on solid potassium hydroxide via a vacuum gas–solid reaction. Imine–enamine tautomerism has been demonstrated at room temperature for the most kinetically stable derivatives.

Graphical abstract: Synthesis of N-unsubstituted cycloalkylimines containing a 4 to 8-membered ring

Supplementary files

Article information

Article type
Communication
Submitted
03 Mar 2019
Accepted
12 Apr 2019
First published
12 Apr 2019

Chem. Commun., 2019,55, 5647-5650

Synthesis of N-unsubstituted cycloalkylimines containing a 4 to 8-membered ring

J. Guillemin, W. Nasraoui and H. Gazzeh, Chem. Commun., 2019, 55, 5647 DOI: 10.1039/C9CC01755K

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