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Visible-light-mediated guest trapping in a photosensitizing porous coordination network: metal-free C–C bond-forming modification of metal–organic frameworks for aqueous-phase herbicide adsorption

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Abstract

A series of furan/thiophene-derived Cr-MIL-101s were obtained via visible-light-mediated C–C bond-forming catalysis within photosensitizing porous materials. The guest trapping process was achieved under very mild and metal-free conditions, affording newly functionalized MOFs with more π–π stacking, hydrogen bonding properties and excellent adsorption capacity in removing herbicides from aquatic environments.

Graphical abstract: Visible-light-mediated guest trapping in a photosensitizing porous coordination network: metal-free C–C bond-forming modification of metal–organic frameworks for aqueous-phase herbicide adsorption

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Publication details

The article was received on 17 Feb 2019, accepted on 08 Apr 2019 and first published on 08 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC01371G
Citation: Chem. Commun., 2019, Advance Article

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    Visible-light-mediated guest trapping in a photosensitizing porous coordination network: metal-free C–C bond-forming modification of metal–organic frameworks for aqueous-phase herbicide adsorption

    Y. Yang, J. Che, B. Wang, Y. Wu, B. Chen, L. Gao, X. Dong and J. Zhao, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC01371G

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