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Photooxygenation of 2-propargylfurans: a path to structurally diverse nitrogen-containing 5-membered rings

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Abstract

The photooxygenation of 2-propargylfurans enabled access to original nitrogen-containing cyclopentenones and related compounds in a one-pot fashion. By employing readily-available substrates such as furans and amines, we succeeded in achieving a high degree of molecular complexity. Relying on the introduction of an alkyne moiety and tailored substrates, this transformation reveals a new facet for reaction sequences featuring the photooxygenation of furans.

Graphical abstract: Photooxygenation of 2-propargylfurans: a path to structurally diverse nitrogen-containing 5-membered rings

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Publication details

The article was received on 11 Feb 2019, accepted on 04 Apr 2019 and first published on 04 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC01197H
Citation: Chem. Commun., 2019, Advance Article

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    Photooxygenation of 2-propargylfurans: a path to structurally diverse nitrogen-containing 5-membered rings

    L. Marin, G. Force, R. Guillot, V. Gandon, E. Schulz and D. Lebœuf, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC01197H

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