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Issue 39, 2019
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Optimizing electron transfer from CdSe QDs to hydrogenase for photocatalytic H2 production

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Abstract

A series of viologen related redox mediators of varying reduction potential has been characterized and their utility as electron shuttles between CdSe quantum dots and hydrogenase enzyme has been demonstrated. Tuning the mediator LUMO energy optimizes the performance of this hybrid photocatalytic system by balancing electron transfer rates of the shuttle.

Graphical abstract: Optimizing electron transfer from CdSe QDs to hydrogenase for photocatalytic H2 production

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Publication details

The article was received on 08 Feb 2019, accepted on 11 Apr 2019 and first published on 11 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC01150A
Chem. Commun., 2019,55, 5579-5582

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    Optimizing electron transfer from CdSe QDs to hydrogenase for photocatalytic H2 production

    M. L. K. Sanchez, C. Wu, M. W. W. Adams and R. B. Dyer, Chem. Commun., 2019, 55, 5579
    DOI: 10.1039/C9CC01150A

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